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“Living” free radical ring-opening polymerization of 2-methylene-4-phenyl-1,3-dioxolane by atom transfer radical polymerization

✍ Scribed by Cai-Yuan Pan; Xu-Dong Lou


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
80 KB
Volume
201
Category
Article
ISSN
1022-1352

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Radical polymerization of ortho-(1,3-dio
✍ Tsuneyuki Sato; Sumio Shimooka; Makiko Seno 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 232 KB

The polymerization of o- (1,3-dioxolan-2-yl)phenyl ethyl fumarate (DOPEF) initiated with dimethyl 2,2-azobisiso-butyrate (MAIB) was studied kinetically in benzene. The polymerization rate (R p ) at 60ЊC was given by R p Å k [MAIB] 0.76 [DOPEF] 0.71 . The overall activation energy of polymerization w