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Synthesis and pyrolysis of perfluoroazo-2-propane

✍ Scribed by K. V. Scherer Jr.; L. Batt; P. H. Stewart

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
572 KB
Volume
26
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

An improved method has been used to synthesize perfluoroazo‐2‐propane. Pyrolysis over the temperature range 450–514 K in a static system has been shown to be a homogeneous, first‐order process. No pressure dependence was observed in the presence of excess inert gas (SF~6~). The only products were nitrogen and perfluoro‐2,3‐dimethylbutane. The rate constant (k) for the decomposition process is given by:
These results lead to a straightforward mechanism for the decomposition process
equation image
The results are compared with those for other azo compounds. © 1994 John Wiley & Sons, Inc.

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