✦ LIBER ✦

Synthesis and Diels-Alder reaction of trans-3-cyanoacrolein and its acetal

✍ Scribed by F. Fariñia; P. Victory

Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 208 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)88392-1

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✦ Synopsis

As a part of our studies on acylacrylic acids and derivatives (1). we have been attempting to synthesize -3-cyanoacrolein, a compound which promised to react as an active dienophile in the Diela-Alder reaction and seemed to be an attractive intermediate in organic aynthesie. It haa been only recently, in connection with the high polymer chemistry. that two synthesis of this compound have been described (2, 3).

We wish to report a new synthetic route to u-3-cyanoacrolein and its diethylacetal,

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