Molecular aggregation and its applicability to synthesis. The Diels-Alder reaction
โ Scribed by Tambra Dunams; William Hoekstra; Michael Pentaleri; Dennis Liotta
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 241 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
The rates of mtermolecular Dtels-Alder reactions mvolvmg relattvely hydrophobtc dtenes and
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As a part of our studies on acylacrylic acids and derivatives (1). we have been attempting to synthesize -3-cyanoacrolein, a compound which promised to react as an active dienophile in the Diela-Alder reaction and seemed to be an attractive intermediate in organic aynthesie. It haa been only recentl
## Abstract For Abstract see ChemInform Abstract in Full Text.
A short synthesis and resolution of (1R,5R,6R)-6-aminospiro[4.4]nonan-1-ol, 11, is reported. The pivalamide derivative (+)-5 gives excellent diastereo-and regiocontrol as well as endo selectivity as a chiral auxiliary in the BCl 3 -catalyzed Diels-Alder reaction with a variety of symmetrical and uns