Application of the isoselective relationship to diels-alder reactions
β Scribed by Bernd Giese; Joachim Stellmach; Otto Exner
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 161 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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Substituted benzynes can be trapped intramolecularty by an attached furan moiety and such a reaction has been used in the synthesis of the natura'LZy occurring o-naphthoquinone mansonone E. The intramolecular Diels-Alder reaction continues to enjoy considerable popularity, particularly in its appli
A review of advances in the applications of the Diels-Alder reaction in organosilicon chemistry in our laboratory is presented. Using this reaction, we have synthesized a series of organosilicon monomers and polymers with polyphenyl groups and condensed rings and established a novel vulcanization sy