Diels-alder Reactions of Azadienes: Scope and Applications
β Scribed by Dale L. Boger
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 781 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0037-9646
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π SIMILAR VOLUMES
Diels-Alder Reactions of N-Silyloxy 1-Azadienes. -The novel N-silyloxy 1-azadienes (III) undergo Diels-Alder reaction with various quinones or N-phenylmaleimide to give the corresponding pyridine derivatives, thus establishing a convenient access to this class of compounds. -(BEHFOROUZ,
Inter-and Intramolecular Diels-Alder Reaction of Benzoxazole-Based Azadienes. -The title reactions are very selective. The preparation of the starting materials (I), which behave as inverse-type dienes, is given. -
## Abstract A summary of the applications of the inverse electron demand DielsβAlder reactions of heterocyclic and acyclic azadienes in the total synthesis of natural products is provided and a recent application in the total synthesis of nothapodytine B (mappicine ketone) is presented in detail.