Some applications of the diels–alder reaction in organosilicon chemistry
✍ Scribed by Huayu Qiu; Weiyong Yu; Zuodong Du
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 629 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0268-2605
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✦ Synopsis
A review of advances in the applications of the Diels-Alder reaction in organosilicon chemistry in our laboratory is presented. Using this reaction, we have synthesized a series of organosilicon monomers and polymers with polyphenyl groups and condensed rings and established a novel vulcanization system for silicone rubber. In addition, we discuss the influences of the large aromatic groups on the properties of the polymers.
📜 SIMILAR VOLUMES
The Mitsunobu reaction ± the nucleophilic substitution of an alcoholic hydroxyl group mediated by the redox system trialkylphosphine/dialkyl azodicarobxylate ± is widely used in the chemistry of biologically active compounds. The paper deals with applications of the Mitsunobu reaction in amino acid