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Synthesis and Crystal Structures of Two Novel Anionic Aluminophosphates: A One-Dimensional Chain, UT-7 ([Al 3 P 5 O 20 H] 5- [C 7 H 13 NH 3+ ] 5 ), and a Layer Containing Two Cyclic Amines, UT-8 ([Al 3 P 4 O 16 ] 3- [C 4 H 7 NH 3+ ] 2 [C 5 H 10 NH 2+ ])

โœ Scribed by Oliver, Scott; Kuperman, Alex; Lough, Alan; Ozin, Geoffrey A.


Book ID
126989728
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
845 KB
Volume
35
Category
Article
ISSN
0020-1669

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The first example of an aluminophosphate containing organic anions covalently bonded to the framework of the structure is reported was prepared hydrothermally and adopts a layered structure. The oxalate groups act as bidentate ligands to Al 3ุ‰ and hold the structure together by strong interlayer P-