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An Example of a Reactive Template in the Synthesis of a Novel Layered Aluminum Phosphate, (Al3P4O16)3-(NH3(CH2)5NH3)2+(C5H10NH2)+

✍ Scribed by A.M. Chippindale; S. Natarajan; J.M. Thomas; R.H. Jones


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
298 KB
Volume
111
Category
Article
ISSN
0022-4596

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✍ Philip Lightfoot; Zoe A.D. Lethbridge; Russell E. Morris; David S. Wragg; Paul A πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 English βš– 143 KB

The first example of an aluminophosphate containing organic anions covalently bonded to the framework of the structure is reported was prepared hydrothermally and adopts a layered structure. The oxalate groups act as bidentate ligands to Al 3Ψ‰ and hold the structure together by strong interlayer P-