✦ LIBER ✦

Synthesis and Structure of an Unusual New Layered Aluminophosphate Containing Oxalate Groups, [NH3CH2CH2NH3]2.5[Al4H(HPO4)4(H2PO4)2(C2O4)4]

✍ Scribed by Philip Lightfoot; Zoe A.D. Lethbridge; Russell E. Morris; David S. Wragg; Paul A. Wright; Åke Kvick; Gavin B.M. Vaughan

Publisher: Elsevier Science
Year: 1999
Tongue: English
Weight: 143 KB
Volume: 143
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.1998.8081

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✦ Synopsis

The first example of an aluminophosphate containing organic anions covalently bonded to the framework of the structure is reported

was prepared hydrothermally and adopts a layered structure. The oxalate groups act as bidentate ligands to Al 3؉ and hold the structure together by strong interlayer P-O-H-oxalate hydrogen bonds. The structure was solved from synchrotron X-ray diffraction data collected on a very small single crystal, space group C2/m, a ‫؍‬ 19.683(4) A s , b ‫؍‬ 12.360(3) A s , c ‫؍‬ 16.734(3) A s , ‫؍‬ 110.51(3)°.

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