Formation of a New Layered Aluminophosphate [Al 3 P 4 O 16 ][C 5 N 2 H 9 ] 2 [NH 4 ]
โ Scribed by Yu, J.; Li, J.; Sugiyama, K.; Togashi, N.; Terasaki, O.; Hiraga, K.; Zhou, B.; Qiu, S.; Xu, R.
- Book ID
- 126227385
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 102 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0897-4756
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๐ SIMILAR VOLUMES
The title compound (named MU-~) is a new layered aluminophosphate with a unusual Al/P ratio for this kind of materials. Mu-4 was obtained From a quasi nonaqueous mixture involving mainly diethylfonnamide (DEF) as solvent, in addition to limited amounts of water. DEF is decomposed during the synthesi
The first example of an aluminophosphate containing organic anions covalently bonded to the framework of the structure is reported was prepared hydrothermally and adopts a layered structure. The oxalate groups act as bidentate ligands to Al 3ุ and hold the structure together by strong interlayer P-