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Synthesis and Chemistry of [Hydrotris(3,5-bis(trifluoromethyl)pyrazolyl)borato]silver(I) Complexes

✍ Scribed by Dias, H. V. Rasika; Wang, Ziyun; Jin, Wiechang

Book ID
127358475
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
297 KB
Volume
36
Category
Article
ISSN
0020-1669

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An improved synthesis of 3,5-bis(trifluoromethyl)pyrazole (1) is described. This compound was used for the high-yield syntheses of the tris(pyrazoly1)borates Nd [HB(3,,-pz),1 (2a) and the corresponding potassium salt, 2b, starting from 1 and NaBH, and KBH,, respectively. A convenient route to the co

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The title compound, [Cu(C 15 H 4 BF 18 N 6 )(C 2 H 3 N)] or [HB(3,5-(CF 3 ) 2 Pz) 3 ]Cu I (CH 3 CN), was synthesized from [Cu I (CF 3 -SO 3 )] 2 ÁC 6 H 5 CH 3 and[HB(3,5-(CF 3 ) 2 Pz) 3 ]Na(H 2 O) in CH 2 Cl 2 /CH 3 CN. The Cu I atom adopts a distorted tetrahedral geometry and is coordinated by four