𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and Structure of [Hydridotris(3,5-bis(trifluoromethyl)pyrazolyl)borato]potassium

✍ Scribed by Dias, H. V. Rasika; Lu, Hui-Ling; Ratcliff, Robert E.; Bott, Simon G.

Book ID
120195580
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
209 KB
Volume
34
Category
Article
ISSN
0020-1669

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

(Acetonitrile){hydridotris[3,5-bisΒ­(trif
(Acetonitrile){hydridotris[3,5-bisΒ­(trifluoroΒ­methΒ­yl)-1-pyrazolΒ­yl]borato}copper(I)
✍ Balili, Marielle Nicole C. ;Pintauer, Tomislav πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 132 KB

The title compound, [Cu(C 15 H 4 BF 18 N 6 )(C 2 H 3 N)] or [HB(3,5-(CF 3 ) 2 Pz) 3 ]Cu I (CH 3 CN), was synthesized from [Cu I (CF 3 -SO 3 )] 2 ÁC 6 H 5 CH 3 and[HB(3,5-(CF 3 ) 2 Pz) 3 ]Na(H 2 O) in CH 2 Cl 2 /CH 3 CN. The Cu I atom adopts a distorted tetrahedral geometry and is coordinated by four

High-Yield Syntheses of Sodium, Potassiu
High-Yield Syntheses of Sodium, Potassium, and Thallium Hydrotris[3,5-bis(trifluoromethyl)pyrazolyl]borates and the X-ray crystal structure of {hydrotris[3,5-bis(trifluoromethyl)pyrazolyl]borato} thallium(I)
✍ Oliver Renn; Luigi M. Venanzi; Arianna Marteletti; Volker Gramlich πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 German βš– 588 KB

An improved synthesis of 3,5-bis(trifluoromethyl)pyrazole (1) is described. This compound was used for the high-yield syntheses of the tris(pyrazoly1)borates Nd [HB(3,,-pz),1 (2a) and the corresponding potassium salt, 2b, starting from 1 and NaBH, and KBH,, respectively. A convenient route to the co