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(Acetonitrile){hydridotris[3,5-bis­(trifluoro­meth­yl)-1-pyrazol­yl]borato}copper(I)

✍ Scribed by Balili, Marielle Nicole C. ;Pintauer, Tomislav

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
132 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cu(C 15 H 4 BF 18 N 6 )(C 2 H 3 N)] or [HB(3,5-(CF 3 ) 2 Pz) 3 ]Cu I (CH 3 CN), was synthesized from [Cu I (CF 3 -SO 3 )] 2 ÁC 6 H 5 CH 3 and[HB(3,5-(CF 3 ) 2 Pz) 3 ]Na(H 2 O) in CH 2 Cl 2 /CH 3 CN. The Cu I atom adopts a distorted tetrahedral geometry and is coordinated by four N atoms, three N atoms from the tridentate tris(pyrazolyl)borate ligand [Cu-N = 2.0992 (12) A ˚] and one N atom from acetonitrile [Cu-N = 1.888 (3) A ˚]. The acetonitrile ligand is linear. The Cu atom, acetonitrile ligand, B and its attached H atom lie on a crystallographic threefold rotation axis.

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