Synthesis and characterization of rhenium(VII) oxide complexes of phenothiazines

✍ Scribed by Netkal M. Made Gowda; Hnin P. Phyu; Brian E. Ackerson

• Publisher: Springer
• Year: 1993
• Tongue: English
• Weight: 377 KB
• Volume: 18
• Category: Article
• ISSN: 0340-4285
• DOI: 10.1007/bf00136053

✦ Synopsis

Five complexes of rhenium(VII) oxide with N-alkylphenothiazines have been synthesized and characterized on the basis of elemental analyses, molar conductances, and u.v.-vis., i.r. and n.m.r, spectral data. The molecular formulas of the new ionic complexes are: [ReO3(PTZ)z(HzO)]-[ReO4], PTZ = chlorpromazine, promethazine or ethopropazine; [ReO3(TF)(H20)][ReO4] , TF = trifluoperazine; and [ReO3(TR)3][ReO4(HzO)2].H20 , TR = thioridazine. Tentative structures have been proposed.