Hydrido complexes of rhenium: Synthesis and reactivity
β Scribed by D Guisto
- Publisher
- Elsevier Science
- Year
- 1972
- Weight
- 818 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0073-8085
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π SIMILAR VOLUMES
New organoplatinum-rhenium heterobimetallic complexes (organic ligand = Me (1), Et (2), CH2Ph (3), Ph (4)) with sulfur ligands have been prepared and characterized by IR, IH and 13c{1n} NMR, elemental analysis, and chemical reactions. Complex 1 was thermally more stable than related PtMeCi(cod) (5)
The five-coordinate compound [RuHCl(CO)(PiPr 2 Ph) 2 ] (1), [RuHCl 2 (CO)(PiPr 2 Ph) 2 ] -contains the chloro ligands in cis and the phosphanes in trans disposition. The Ru=CH 2 bond which was prepared from RuCl 3 β’ 3 H 2 O and PiPr 2 Ph in methanol in the presence of NEt 3 , reacts with CO and wit