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Synthesis and characterization of a planarized, trimethylenemethane-type bis(semiquinone) biradical

✍ Scribed by David A. Shultz; Hyoyoung Lee; Rosario M. Fico Jr.


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
412 KB
Volume
55
Category
Article
ISSN
0040-4020

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✦ Synopsis


The synthesis and characterization of a biradical in which two ~miquinoue rings a¢ held flgidly co-p~n~r and are a nach.d in a geathml fashion to a carlton-cain double bond is described. The insulin of cyclic voltammeaT and vadable-tempeman¢ EPR studies are fam~eted in terms of the interaction of the two semiquinones through the carbou-carbou double bond coupling uniL


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