Synthesis and antiviral activity of phosphonium salts
✍ Scribed by G. V. Romanov; O. K. Pozdeev; G. Kh. Gil'manova; T. Ya. Ryzhikova; É. P. Semkina
- Book ID
- 112400980
- Publisher
- Springer
- Year
- 1990
- Tongue
- English
- Weight
- 296 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0091-150X
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📜 SIMILAR VOLUMES
A short and efficient synthesis of the two enantiomeric iron-complcxed phosphonium salts (+)-1 and (-)-2 is described. Upon reaction with the chiral fotmyloxirane 3, the corresponding chiral ylides exhibit quite difietent mactivities. Few examples of Wittig-type reactions with phosphotus or sulphur
In CC14 solution the singlet signal for the hydroxymethyl group is at T = 6.68 (3 H), but in dimethyl sulfoxide there arc two signals with relative areas 1:2 (OH;CH2). The signal for the vinyl protons occurs at T = 5.42 (2 H). Infrared spectrum: 880, 1640, 1770, 3070 (=CH2), 1035, 3360 (broad associ
the mother liquors produce further 16 %. After being washed with cold ethanol and ether, the crystals are analytically pure. The proton magnetic resonance spectrum 141 gave the following data (numbers indicate p.p.m with tetramethylsilane as standard) : Si(CH& Si-CHz-Si S-CHI-C C-CH2-0 0.6 3.0 3.8 4