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Radiation-Chemical Synthesis of Phosphonium and Arsonium Salts

✍ Scribed by Dr. H. Drawe; Dipl.-Chem. G. Caspari

Publisher: John Wiley and Sons
Year: 1966
Tongue: English
Weight: 205 KB
Volume: 5
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.196603172

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✦ Synopsis

In CC14 solution the singlet signal for the hydroxymethyl group is at T = 6.68 (3 H), but in dimethyl sulfoxide there arc two signals with relative areas 1:2 (OH;CH2). The signal for the vinyl protons occurs at T = 5.42 (2 H). Infrared spectrum: 880, 1640, 1770, 3070 (=CH2), 1035, 3360 (broad association band), 3630 (primary OH), and 1365 cm-1 (CH3). Thc infrared spectrum of the alcohol (2) is identical with that of a sample prepared by reducing l-n~ethyl-4-metitylenccyclohexanc-I-carboxylic acid [21 with LiAlH4.

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