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Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands§

✍ Scribed by Scholl, Matthias; Ding, Sheng; Lee, Choon Woo; Grubbs, Robert H.


Book ID
111889434
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
59 KB
Volume
1
Category
Article
ISSN
1523-7060

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A new class of ruthenium based catalysts coordinated with a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and a Schiff base ligand have been tested in ring-closing metathesis and ring-opening metathesis polymerization reactions. The results obtained point out that the synergy of Schiff base ligands wi

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Increased Ring Closing Metathesis Activity of Ruthenium-Based Olefin. Metathesis Catalysts Coordinated with Imidazolin-2-ylidene Ligands. -A novel air-and water-tolerant, imidazolinyl-substituted Ru-catalyst for ring closing metathesis reaction is presented. It exhibits remarkably increased activit