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ChemInform Abstract: Increased Ring Closing Metathesis Activity of Ruthenium-Based Olefin. Metathesis Catalysts Coordinated with Imidazolin-2-ylidene Ligands.

✍ Scribed by Matthias Scholl; Tina M. Trnka; John P. Morgan; Robert H. Grubbs

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199925048

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✦ Synopsis

Increased Ring Closing Metathesis Activity of Ruthenium-Based Olefin. Metathesis Catalysts Coordinated with Imidazolin-2-ylidene Ligands.

-A novel air-and water-tolerant, imidazolinyl-substituted Ru-catalyst for ring closing metathesis reaction is presented. It exhibits remarkably increased activity at elevated temperature compared to the standard RuCl 2 (=CHPh)(PCy 3 ) 2 catalyst.

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