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A New Ruthenium-Based Olefin Metathesis Catalyst Coordinated with 1,3-Dimesityl-1,4,5,6-tetrahydropyrimidin-2-ylidene: Synthesis, X-ray Structure, and Reactivity

✍ Scribed by Yun, Jaesook; Marinez, Eric R.; Grubbs, Robert H.


Book ID
118147695
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
56 KB
Volume
23
Category
Article
ISSN
0276-7333

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Activity of a new class of ruthenium bas
✍ Bob De Clercq; Francis Verpoort πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 125 KB

A new class of ruthenium based catalysts coordinated with a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and a Schiff base ligand have been tested in ring-closing metathesis and ring-opening metathesis polymerization reactions. The results obtained point out that the synergy of Schiff base ligands wi