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Increased ring closing metathesis activity of ruthenium-based olefin metathesis catalysts coordinated with imidazolin-2-ylidene ligands

✍ Scribed by Matthias Scholl; Tina M. Trnka; John P. Morgan; Robert H. Grubbs

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
213 KB
Volume
40
Category
Article
ISSN
0040-4039

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A new class of ruthenium based catalysts coordinated with a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and a Schiff base ligand have been tested in ring-closing metathesis and ring-opening metathesis polymerization reactions. The results obtained point out that the synergy of Schiff base ligands wi