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Synthesis and Absolute Configuration of New Trichloro Steroids with Cyclopropane-Containing Side Chains

✍ Scribed by Robert W. Lang; Carl Djerassi; Phyllis D. Strong; Dale C. Swenson; William L. Duax

Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
372 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The determination of the absolute configuration of the trichloro steroids 2a and 2c (cf. Scheme 1) by means of two X‐ray crystal structure analyses is reported and applies also to the determination of the absolute configurations of several derived steroidal cyclopropanes [1]. The preparation of the chlorinated derivatives 2a‐c is described and the spectroscopic properties of 1 and 2 are summarized.

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