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Sterols with Cyclopropane-Containing Side Chains: Synthesis and Acid Isomerization

✍ Scribed by Claudio Tarchini; Michel Rohmer; Carl Djerassi

Publisher
John Wiley and Sons
Year
1979
Tongue
German
Weight
442 KB
Volume
62
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

To test the eventual involvement of sterols with a cyclopropane containing side chain in bio‐methylation processes, 24,25‐methanocholest‐5‐en‐3β‐ol (5) and 24,25‐methano‐26‐methylcholest‐5‐en‐3β‐ol (6) were synthesized. Together with the naturally occurring cyclopropane petrosterol (1), they were submitted to acid isomerization to provide chemical models for some of their potential metabolites.

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