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Synthesis, absolute configuration, and analysis of malathion, malaoxon, and isomalathion enantiomers

✍ Scribed by Berkman, Clifford E.; Thompson, Charles M.; Perrin, Scott R.

Book ID
126988404
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
833 KB
Volume
6
Category
Article
ISSN
0893-228X

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📜 SIMILAR VOLUMES

Simple syntheses of malathion and malaox
Simple syntheses of malathion and malaoxon enantiomers, and isomalathion diastereoisomers: toxicity-configuration relationship
✍ Połeć, Iwona; Cieślak, Ludwika; Śledziński, Bohdan; Ksycińska, Hanna 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 247 KB

Malathion enantiomers were synthesized by nucleophilic substitution of O,O-dimethyl dithiophosphoryl anion to diethyl (R)-or (S)-2-bromosuccinate. Malaoxon enantiomers were obtained from optically active malathions in thionoÈthiolo rearrangement with 65% Desmethylation of malathion HNO 3 . enantiome