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Stereoselective toxicity of malathion and its metabolites, malaoxon and isomalathion

✍ Scribed by Anping Zhang; Xuemei Xie; Jing Ye; Chunmian Lin; Xiaoyan Hu


Book ID
106313146
Publisher
Springer-Verlag
Year
2010
Tongue
English
Weight
185 KB
Volume
9
Category
Article
ISSN
1610-3653

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Simple syntheses of malathion and malaox
✍ Połeć, Iwona; Cieślak, Ludwika; Śledziński, Bohdan; Ksycińska, Hanna 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 247 KB

Malathion enantiomers were synthesized by nucleophilic substitution of O,O-dimethyl dithiophosphoryl anion to diethyl (R)-or (S)-2-bromosuccinate. Malaoxon enantiomers were obtained from optically active malathions in thionoÈthiolo rearrangement with 65% Desmethylation of malathion HNO 3 . enantiome