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Additions and Corrections. Synthesis, Absolute Configuration, and Analysis of Malathion, Malaoxon, and Isomalathion Enantiomers

✍ Scribed by Berkman, Clifford; Thompson, Charles; Perrin, Scott

Book ID
126892978
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
106 KB
Volume
7
Category
Article
ISSN
0893-228X

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πŸ“œ SIMILAR VOLUMES

Simple syntheses of malathion and malaox
Simple syntheses of malathion and malaoxon enantiomers, and isomalathion diastereoisomers: toxicity-configuration relationship
✍ PoΕ‚eΔ‡, Iwona; CieΕ›lak, Ludwika; ŚledziΕ„ski, Bohdan; KsyciΕ„ska, Hanna πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 247 KB

Malathion enantiomers were synthesized by nucleophilic substitution of O,O-dimethyl dithiophosphoryl anion to diethyl (R)-or (S)-2-bromosuccinate. Malaoxon enantiomers were obtained from optically active malathions in thionoÈthiolo rearrangement with 65% Desmethylation of malathion HNO 3 . enantiome