Am Bruckenkopf substituierte Bicyclo-[2,2,2]-octane (I) sind als stereochemisch weitgehend definierte Systeme zum Studium theoretischer und mechanistischer Fragen besonders geeignet l). Trotz der Beachtung, welche diese Verbindungen daher in letzter Zeit gefunden haben, sind sie aber keineswegs leic
Synthese und BECKMANN-Umlagerung von 1-Acetyl-bicyclo [2.2.2] octan-oxim. Bicyclo [2.2.2] octan-Reihe, 8. Mitteilung
✍ Scribed by H. J. Fischer; C. A. Grob
- Publisher
- John Wiley and Sons
- Year
- 1964
- Tongue
- German
- Weight
- 300 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0018-019X
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## Abstract The behaviour of bicyclo [2.2.2]octa‐2,5‐diene (1) towards perbenzoic acid, 2,4 dinitrophenylsulfenyl chloride and ozone has been studied. In no instance was the formation of a homotricyclene derivative by homoconjugative addition observed. However, the primary formation of homoallylic
SS2-e HS,-=Z H,S, were obtained readily, furnishing the pK's of H,S,. The solutions of the lower polysulfides, however, do not contain simply the anions present in the lattice of the solid salt. As soon as the solid salts are dissolved disproportionation reactions take place giving rise to mixtures.