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Synthese Du Tertiobutyl-2 dinitro-4,6 Phenol Noyau-14C (U) (“Dinoterbe” Noyau-14C)

✍ Scribed by Jean-Pierre Noel; Louis Pichat; Achille Benakis

Publisher
John Wiley and Sons
Year
1980
Tongue
French
Weight
288 KB
Volume
17
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

(U‐^14^C) Phenol and isobutene under pressure in presence of aluminium phenoxide gave in 60 % yield a mixture of (ring U‐^14^C) 2‐t‐butylphenol (50 %) and (ring U‐^14^C)‐2,6‐di‐t‐butylphenol (10 %) which were separated by column chromatography on silicagel. Each t‐butylphenol was nitrated under appropriate conditions to give an 35 % overall yield of (ring‐U‐^14^C)‐4,6‐dinitro‐2‐t‐butylphenol : specific activity : 27.4 mCi/mMol which was proved by TLC and HPLC to be 99 % radiochemically pure.

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