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Synthese des 3-Methylnaphth[2,3-c]isoxazols

✍ Scribed by Friedrichsen, Willy ;Kaschner, Peter

Publisher
Wiley (John Wiley & Sons)
Year
1977
Weight
256 KB
Volume
1977
Category
Article
ISSN
0074-4617

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✦ Synopsis

Abstract

Aus 3′‐ Amino‐2‐acetonaphthon (7c) erhält man durch Diazotierung und anschließende Umsetzung mit Natriumazid das 3′‐Azido‐2′‐acetonaphthon (9). Daraus läßt sich durch thermische Stickstoffabspaltung ein linear benzanelliertes Anthranil, das 3‐Methylnapth[2,3‐c]‐isoxazol (5) darstellen.

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