Synthese von [1]Benzothieno[2,3—d]isoxazol-Derivaten
✍ Scribed by F. Sauter; G. Büyük
- Publisher
- Springer Vienna
- Year
- 1974
- Tongue
- English
- Weight
- 279 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0026-9247
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📜 SIMILAR VOLUMES
The reaction of the transient furoisoxazole 4 with dimethyl acetylenedicarboxylate results in the formation of oxepine $&. The boat-shaped structure of s has been confirmed by X-ray crystallography. The experimental findings are in accord with quantum chemical calculations (AMl, PM3).
Synthesis of 2,4‐Diamino‐thieno[2,3‐__d__]pyrimidines Condensation of 2‐aminothiophene‐3‐carbonitrile (4) with guanidine or sequential addition of CS~2~ and NH~3~ to 4 provides 2,4‐diaminothieno[2,3‐__d__]pyrimidine (7). This compound yields, after sequential addition of __sec__‐BuLi and either [3‐