✦ LIBER ✦

Symmetrical Bis(acetylido)ruthenium(II) Complexes

✍ Scribed by Leslie D. Field; Alison M. Magill; Timothy K. Shearer; Scott J. Dalgarno; Mohan M. Bhadbhade

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 498 KB
Volume: 2011
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.201100322

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Symmetrical, mononuclear bis(acetylido)ruthenium(II) complexes were prepared by the reaction of [trans‐RuMe~2~(dmpe)~2~] [dmpe = 1,2‐bis(dimethylphosphanyl)ethane] with terminal alkynes. The complexes were characterised by multinuclear NMR spectroscopy and X‐ray crystallography. In some cases, the complexes catalyse the head‐to‐head dimerisation of terminal alkynes to yield organic butenynes. The regiochemistry of this dimerisation depends on the solvent used; methanol results in the isolation of (Z)‐butenynes, whereas toluene gives predominantly (E) isomers.

📜 SIMILAR VOLUMES

Bis(acetylido) Complexes of Ruthenium(II

Bis(acetylido) Complexes of Ruthenium(II) Bearing Monodentate Phosphane Ligands

✍ Leslie D. Field; Alison M. Magill; Scott J. Dalgarno; Paul Jensen 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 378 KB

## Abstract Terminal acetylenes react with __cis__‐RuMe~2~(PMe~3~)~4~ to form the bis(acetylido) complexes __cis__/__trans__‐Ru(C≡CR)~2~(PMe~3~)~4~ in good yield. The structures of __trans__‐2 (R = Ph), __cis__‐3 (R = __p__‐C~6~H~4~‐OMe), __trans__‐4 (R = __p__‐C~6~H~4~‐Me), __cis__‐6 (R = Me), __t

Synthesis of Flexible Bis-Intercalating

Synthesis of Flexible Bis-Intercalating Ruthenium(II) Complexes

✍ Craig R. Brodie; Janice R. Aldrich-Wright 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 279 KB

A Ruthenium(II) Complex with a Tetradent

A Ruthenium(II) Complex with a Tetradentate C2-Symmetric Bis(phosphino)-bis(oxazoline) Ligand for Asymmetric Transfer Hydrogenation of Aromatic Ketones.

✍ Sang-gi Lee; Hyo Ryung Jung; Kwan Mook Kim; Choong Eui Song; Cheon Gyo Cho 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 88 KB 👁 1 views

Pyrene-Bridged Bis(phenanthroline) Ligan

Pyrene-Bridged Bis(phenanthroline) Ligands and Their Dinuclear Ruthenium(II) Complexes

✍ Latif Chouai; Feiyue Wu; Youngchan Jang; Randolph P. Thummel 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 176 KB

Resonance Raman spectra of tris(violurat

Resonance Raman spectra of tris(violurate)ruthenium(II) and of mixed (violurate)bis(2,2′-bipyridine)ruthenium(II) complexes

✍ V. R. L. Constantino; H. E. Toma; L. F. C. de Oliveira; P. S. Santos 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 312 KB

## Abstract The existence of two independent chromophores in [Ru(bipy)~2~(H~2~V)]^+^, where H~2~V^−^ = violurate anion and bipy = 2,2′bipyridine, was demonstrated by comparing its resonance Raman spectra with those displayed by the [Ru(H~2~V)~3~]^−^ analogue. In the former, the electronic band at 4

Ruthenium(II, III) Dimeric Complexes

✍ Dr. J. K. Nicholson 📂 Article 📅 1967 🏛 John Wiley and Sons 🌐 English ⚖ 239 KB

2. 227 mg of cysteamine and 392 mg of Mohr's salt are dissolved in 50 ml of 1 M tris-HC1 buffer (pH = 7.0). The p H is then adjusted to 9.5 by 1 N NaOH, and a solution of 504 mg of the sodium salt of riboflavin monophosphate (FMN) in 25 ml of H 2 0 is added. After 5 minutes the mixture is transferre