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Bis(acetylido) Complexes of Ruthenium(II) Bearing Monodentate Phosphane Ligands

✍ Scribed by Leslie D. Field; Alison M. Magill; Scott J. Dalgarno; Paul Jensen


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
378 KB
Volume
2008
Category
Article
ISSN
1434-1948

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✦ Synopsis


Abstract

Terminal acetylenes react with cis‐RuMe~2~(PMe~3~)~4~ to form the bis(acetylido) complexes cis/trans‐Ru(C≡CR)~2~(PMe~3~)~4~ in good yield. The structures of trans‐2 (R = Ph), cis‐3 (R = p‐C~6~H~4~‐OMe), trans‐4 (R = p‐C~6~H~4~‐Me), cis‐6 (R = Me), trans‐7 (R = SiMe~3~) and cis‐8 (R = H) were determined by X‐ray crystallography. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)


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