Bis(acetylido) Complexes of Ruthenium(II) Bearing Monodentate Phosphane Ligands
✍ Scribed by Leslie D. Field; Alison M. Magill; Scott J. Dalgarno; Paul Jensen
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 378 KB
- Volume
- 2008
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
Abstract
Terminal acetylenes react with cis‐RuMe~2~(PMe~3~)~4~ to form the bis(acetylido) complexes cis/trans‐Ru(C≡CR)~2~(PMe~3~)~4~ in good yield. The structures of trans‐2 (R = Ph), cis‐3 (R = p‐C~6~H~4~‐OMe), trans‐4 (R = p‐C~6~H~4~‐Me), cis‐6 (R = Me), trans‐7 (R = SiMe~3~) and cis‐8 (R = H) were determined by X‐ray crystallography. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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