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Synthesis of New Half-Sandwich Ruthenium(II) Complexes Bearing Alkenyl- and Alkynylphosphane Ligands

✍ Scribed by Josefina Díez; M. Pilar Gamasa; José Gimeno; Elena Lastra; Amparo Villar

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
227 KB
Volume
2006
Category
Article
ISSN
1434-1948

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Bis(acetylido) Complexes of Ruthenium(II
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✍ Leslie D. Field; Alison M. Magill; Scott J. Dalgarno; Paul Jensen 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 378 KB

## Abstract Terminal acetylenes react with __cis__‐RuMe~2~(PMe~3~)~4~ to form the bis(acetylido) complexes __cis__/__trans__‐Ru(C≡CR)~2~(PMe~3~)~4~ in good yield. The structures of __trans__‐2 (R = Ph), __cis__‐3 (R = __p__‐C~6~H~4~‐OMe), __trans__‐4 (R = __p__‐C~6~H~4~‐Me), __cis__‐6 (R = Me), __t