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A New Route to Cationic Half-Sandwich Ruthenium(II) Complexes with Chiral Cyclopentadienylphosphane Ligands.

✍ Scribed by Angelino Doppiu; Albrecht Salzer

Publisher
John Wiley and Sons
Year
2004
Weight
91 KB
Volume
35
Category
Article
ISSN
0931-7597

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Chiral Half-Sandwich Ruthenium(II) Compl
Chiral Half-Sandwich Ruthenium(II) Complexes as Catalysts in 1,3-Dipolar Cycloaddition Reactions of Nitrones with Methacrolein
✍ Daniel Carmona; M. Pilar Lamata; Fernando Viguri; Joaquina Ferrer; Néstor García 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 253 KB 👁 1 views

## Abstract Ruthenium complexes of formula [(η^6^‐arene)Ru(LL\*)(H~2~O)][SbF~6~]~2~ (arene = C~6~H~6~, __p__‐MeC~6~H~4~__i__Pr, C~6~Me~6~; LL\* = bidentate chelate chiral ligand with PN, PP or NN donor atoms) have been tested as catalyst precursors for the asymmetric 1,3‐dipolar cycloaddition of ni