Pyrene-Bridged Bis(phenanthroline) Ligands and Their Dinuclear Ruthenium(II) Complexes
✍ Scribed by Latif Chouai; Feiyue Wu; Youngchan Jang; Randolph P. Thummel
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 176 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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📜 SIMILAR VOLUMES
## Abstract Friedländer reactions of 4‐aminoacridine‐3‐carbaldehyde with 1,3‐, 1,4‐di‐, and 1,3,5‐triacetylbenzenes afforded a series of corresponding (benzo[b]‐1,10‐phenanthrolin‐2‐yl)benzenes as new N,N,C‐polydentates. Reaction with 1,2‐diacetylbenzene afforded 1,2‐di(benzo[b]‐1,10‐phenanthrol‐2‐
## Abstract Terminal acetylenes react with __cis__‐RuMe~2~(PMe~3~)~4~ to form the bis(acetylido) complexes __cis__/__trans__‐Ru(C≡CR)~2~(PMe~3~)~4~ in good yield. The structures of __trans__‐2 (R = Ph), __cis__‐3 (R = __p__‐C~6~H~4~‐OMe), __trans__‐4 (R = __p__‐C~6~H~4~‐Me), __cis__‐6 (R = Me), __t