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Redox Control of Conformation and Luminescence of a Dinuclear Ruthenium(II) Complex with a Bis-dipyridophenazine Bridging Ligand

✍ Scribed by Mara Staffilani; Peter Belser; Luisa De Cola; František Hartl


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
327 KB
Volume
2002
Category
Article
ISSN
1434-1948

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X-ray Structure of a Ruthenium Dinuclear
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The reaction of [Ru(bpy)(tpy)(Ipcyd)] + (bpy = 2,2Ј-bipyridine, tpy = 2,2Ј:6Ј,2ЈЈ-terpyridine, Ipcyd = 4-iodophenylcyanamide anion) with diethynylbenzene in a Sonogashira cross-coupling reaction gives an unprecedentedly long and conjugated dinuclear complex [{[Ru(bpy)(tpy)] 2 (µ-dcpeb)}(BPh 4 ) 2 ]•