Synthesis and Structure of a Novel Copper (II) Dinuclear Complex with 4,4′-Dipyridyl as the Bridge
✍ Scribed by Liu Xiao-Lan; Zhao Ru; Liu Xiao-Hong; Yue Jun-Jie; Yin Yu-Xin; Sun Yun Zhang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 424 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0256-7660
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## Abstract The synthesis, X‐ray crystal structure and magnetic properties of two oxalato‐bridged dinuclear Cu^II^ complexes, [L‐Cu(μ‐ox)Cu‐L](ClO~4~)~2~, where ox = oxalate and L = 1,4,7‐trimethyl‐1,4,7‐triazacyclononane (Me~3~tacn) or 1‐benzyl‐4,7‐dimethyl‐1,4,7‐triazacyclononane (BzMe~2~tacn) ar
The reaction of [Ru(bpy)(tpy)(Ipcyd)] + (bpy = 2,2Ј-bipyridine, tpy = 2,2Ј:6Ј,2ЈЈ-terpyridine, Ipcyd = 4-iodophenylcyanamide anion) with diethynylbenzene in a Sonogashira cross-coupling reaction gives an unprecedentedly long and conjugated dinuclear complex [{[Ru(bpy)(tpy)] 2 (µ-dcpeb)}(BPh 4 ) 2 ]•