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2,4,6-Triacetylphlorogucinol as Threefold Symmetric Bridging Ligand: Synthesis, Structure and Magnetic Properties of the Copper Complex

✍ Scribed by Eike T. Spielberg; Winfried Plass


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
455 KB
Volume
2010
Category
Article
ISSN
1434-1948

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Bis(terdentate) Pyrazole/Pyridine Ligand
✍ Akhilesh Kumar Singh; Jarl Ivar van der Vlugt; Serhiy Demeshko; Sebastian Decher 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 450 KB 👁 2 views

## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~