Synthesis, Crystal Structures, and Magnetic Properties of a Mono- and a Dinuclear Copper(II) Complex of the 2,4,6-Tris(2-pyridyl)-1,3,5-triazine Ligand
✍ Scribed by Thorsten Glaser; Thomas Lügger; Roland Fröhlich
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 152 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~
triphenylphosphanimino)tetrazolo [5,1-a][1,3,5]tri-An improved crystal structure for 2,4,6-triazido-1,3,5-triazine (2) was determined and for the first time a 14 N-NMR azine (1) was synthesized by reaction of cyanuric azide with triphenylphosphane. 1 is characterized by X-ray structural spectrum was