Surface-mediated reactions. 2. Addition of hydrazoic acid to alkenes
β Scribed by Breton, Gary W.; Daus, Kimberlee A.; Kropp, Paul J.
- Book ID
- 120257225
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 611 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
From the standpoint of atom efficiency, [1] nucleophilic additions to alkenes or alcohols instead of alkyl halides are attractive salt-free methods (Scheme 1). Simple alkenes are readily accessible and abundant carbon-atom sources, but intermolecular additions of 1,3-dicarbonyl compounds to simple a
Regio-and stereocontrolled synthesis of vinylstannanes was achieved by intermolecular addition reaction of a~-alkoxycarbonyl-fl-stannylvinyl radicals to activated alkenes. Under high dilution conditions cyclohexene derivatives were obtained via [2+2+2] radical annulation reaction.