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Broensted Acid Mediated Heterogeneous Addition Reaction of 1,3-Dicarbonyl Compounds to Alkenes and Alcohols.

✍ Scribed by Ken Motokura; Noriaki Fujita; Kohsuke Mori; Tomoo Mizugaki; Kohki Ebitani; Kiyotomi Kaneda

Publisher: John Wiley and Sons
Year: 2006
Weight: 33 KB
Volume: 37
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200633050

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From the standpoint of atom efficiency, [1] nucleophilic additions to alkenes or alcohols instead of alkyl halides are attractive salt-free methods (Scheme 1). Simple alkenes are readily accessible and abundant carbon-atom sources, but intermolecular additions of 1,3-dicarbonyl compounds to simple a

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