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Brønsted Acid Mediated Heterogeneous Addition Reaction of 1,3-Dicarbonyl Compounds to Alkenes and Alcohols

✍ Scribed by Ken Motokura; Noriaki Fujita; Kohsuke Mori; Tomoo Mizugaki; Kohki Ebitani; Kiyotomi Kaneda

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 120 KB
Volume: 118
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200504609

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From the standpoint of atom efficiency, [1] nucleophilic additions to alkenes or alcohols instead of alkyl halides are attractive salt-free methods (Scheme 1). Simple alkenes are readily accessible and abundant carbon-atom sources, but intermolecular additions of 1,3-dicarbonyl compounds to simple a

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