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Supported catalysts based on 2,6-bis(imino)pyridyl complex of Fe(II): DRIFTS study of the catalyst formation and data on ethylene polymerization

✍ Scribed by Nina V. Semikolenova; Vladimir A. Zakharov; Evgenii A. Paukshtis; Irina G. Danilova

Book ID
106547999
Publisher
Springer
Year
2005
Tongue
English
Weight
180 KB
Volume
32
Category
Article
ISSN
1022-5528

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A DFT Quantum-Chemical Study of the Stru
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## Abstract Summary: A DFT method has been applied for quantum‐chemical calculations of the molecular structure of charge‐neutral complex LFeMe(ΞΌMe)~2~AlMe~2~ which is formed in system LFeMe~2~ + AlMe~3~ (L = 2,6‐bis(imino)pyridyl). Calculations suggested the formation of highly polarized complex L

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## Abstract The number of active centers (__C__~P~) and propagation rate constant (__k__~P~) for ethylene polymerization with homogeneous catalyst LCoCl~2~ + MAO and supported catalyst LCoCl~2~/SiO~2~ + Al(__i__‐Bu)~3~, where L is 2,6‐(2,6‐(Me)~2~C~6~H~3~N = CMe)~2~C~5~H~3~N, have been determined u