The number of active centers and propagation rate constant in ethylene polymerization with a homogeneous catalyst based on cobalt 2,6-bis[imino]pyridyl complex with methylaluminoxane activator

Ethylene Polymerization over Homogeneous

Ethylene Polymerization over Homogeneous and Supported Catalysts Based on Bis(imino)pyridine Co(II) Complex: Data on the Number of Active Centers and Propagation Rate Constant

✍ Artem A. Barabanov; Gennady D. Bukatov; Vladimir A. Zakharov; Nina V. Semikoleno 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB

## Abstract The number of active centers (__C__~P~) and propagation rate constant (__k__~P~) for ethylene polymerization with homogeneous catalyst LCoCl~2~ + MAO and supported catalyst LCoCl~2~/SiO~2~ + Al(__i__‐Bu)~3~, where L is 2,6‐(2,6‐(Me)~2~C~6~H~3~N = CMe)~2~C~5~H~3~N, have been determined u