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Study of the ethylene polymerization over homogeneous and supported catalysts based on 2,6-bis(imino)pyridyl complexes of Fe(II) and Co(II)

✍ Scribed by N.V Semikolenova; V.A Zakharov; E.P Talsi; D.E Babushkin; A.P Sobolev; L.G Echevskaya; M.M Khysniyarov

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
314 KB
Volume
182-183
Category
Article
ISSN
1381-1169

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πŸ“œ SIMILAR VOLUMES

Kinetic Study of Ethylene Polymerization
Kinetic Study of Ethylene Polymerization Over Supported Bis(imino)pyridine Iron (II) Catalysts
✍ Artem A. Barabanov; Gennady D. Bukatov; Vladimir A. Zakharov; Nina V. Semikoleno πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 146 KB

## Abstract Summary: The number of active centers (__C__~P~) and propagation rate constants (__k__~P~) for polymerization of ethylene with supported catalysts LFeCl~2~/SiO~2~, LFeCl~2~/Al~2~O~3~ and LFeCl~2~/MgCl~2~ (L = 2,6‐(2,6‐(Me)~2~C~6~H~3~Nο£ΎCMe)~2~C~5~H~3~N), activated by an Al(__i__‐Bu)~3~ c

Ethylene Polymerization over Homogeneous
Ethylene Polymerization over Homogeneous and Supported Catalysts Based on Bis(imino)pyridine Co(II) Complex: Data on the Number of Active Centers and Propagation Rate Constant
✍ Artem A. Barabanov; Gennady D. Bukatov; Vladimir A. Zakharov; Nina V. Semikoleno πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 175 KB

## Abstract The number of active centers (__C__~P~) and propagation rate constant (__k__~P~) for ethylene polymerization with homogeneous catalyst LCoCl~2~ + MAO and supported catalyst LCoCl~2~/SiO~2~ + Al(__i__‐Bu)~3~, where L is 2,6‐(2,6‐(Me)~2~C~6~H~3~N = CMe)~2~C~5~H~3~N, have been determined u

Kinetic Peculiarities of Ethylene Polyme
Kinetic Peculiarities of Ethylene Polymerization over Homogeneous Bis(imino)pyridine Fe(II) Catalysts with Different Activators
✍ Artem A. Barabanov; Gennady D. Bukatov; Vladimir A. Zakharov; Nina V. Semikoleno πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 125 KB

## Abstract Summary: Method of polymerization inhibition by radioactive carbon monoxide (^14^CO) has been used to determine the number of active centers (__C__~P~) and propagation rate constant (__k__~P~) for ethylene polymerization with homogeneous complex 2,6‐(2,6‐(Me)~2~C~6~H~3~Nο£ΎCMe)~2~C~5~H~3~

A DFT Quantum-Chemical Study of the Stru
A DFT Quantum-Chemical Study of the Structure of Precursors and Active Sites of Catalyst Based on 2,6-Bis(imino)pyridyl Fe(II) Complexes
✍ Ivan I. Zakharov; Vladimir A. Zakharov πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 325 KB

## Abstract Summary: A DFT method has been applied for quantum‐chemical calculations of the molecular structure of charge‐neutral complex LFeMe(ΞΌMe)~2~AlMe~2~ which is formed in system LFeMe~2~ + AlMe~3~ (L = 2,6‐bis(imino)pyridyl). Calculations suggested the formation of highly polarized complex L