Homogeneous and supported catalysts based on bis(imino)pyridyl Iron(II) complexes for ethylene polymerization
✍ Scribed by V. A. Zakharov; N. V. Semikolenova; T. B. Mikenas; A. A. Barabanov; G. D. Bukatov; L. G. Echevskaya; M. A. Mats’ko
- Book ID
- 110170728
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 178 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0023-1584
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The immobilization of the soluble precatalysts [(ArN C(Me)) 2 C 5 H 3 N]FeCl 2 , where Ar = 2,4,6-trimethylphenyl (A) or 2,6diisopropylphenyl (B), on supports derived from a spherical MgCl 2 -alcohol adduct yields active supported systems for ethylene polymerization. The activity of the supported ca
## Abstract Summary: The number of active centers (__C__~P~) and propagation rate constants (__k__~P~) for polymerization of ethylene with supported catalysts LFeCl~2~/SiO~2~, LFeCl~2~/Al~2~O~3~ and LFeCl~2~/MgCl~2~ (L = 2,6‐(2,6‐(Me)~2~C~6~H~3~NCMe)~2~C~5~H~3~N), activated by an Al(__i__‐Bu)~3~ c