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Substrate directed diastereoselective hydroformylation of acyclic homomethallylic alcohols

✍ Scribed by Breit, Bernhard

Book ID: 120012687
Publisher: Royal Society of Chemistry
Year: 1997
Tongue: English
Weight: 44 KB
Volume: 6
Category: Article
ISSN: 1359-7345
DOI: 10.1039/A608612H

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Substrate directed diastereoselective hydroaminomethylation of methallylic alcohols has been achieved with the aid of the substrate bound catalyst directing o-DPPB-group (o-DPPB = orthodiphenylphosphanyl benzoate). The amines 3-7, 10, 11 have been obtained in fair to good yields in diastereomer rati