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Substituent Effects on Ring Opening of 2-Furylcarbenes: An ab Initio Study

✍ Scribed by Sun, Ying; Wong, Ming Wah


Book ID
127327085
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
72 KB
Volume
64
Category
Article
ISSN
0022-3263

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An Ab Initio Study of Substituent Effect
✍ Alessandro Bongini; Zhining Xia; Mauro Panunzio πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 127 KB πŸ‘ 1 views

## Abstract The electrocyclization of 4‐substituted 3‐silyloxy‐2‐azadienes to β‐lactams was studied at the MP2/6‐31G\* level of theory and the effect of the substituents on the reactivity of the azadiene and on the stereochemistry of the cyclic products was evaluated. It was shown that the electroc